Iranian Journal of Materials Science and Engineering

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Sago hampas was chemically modified through esterification process to adsorb both laboratory and commercial synthesized ZnO nanoparticles from water in a batch adsorption studies. The esterified sago hampas (ECSH) as a biosorbent w:as char:acterized using Energy dispersive X-ray spectroscopy (EDX), Fourier-transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), and Brunauer-Emmett-Teller (BET) technique s. Investigating the effect of pH, contact time, initial sorbate ion concentration, temperature and sorbent mass were carried out where adsorption parameters were analyzed using Langmuir, Freundlich and Temkin models. The correlation between kinetics of adsorption and tgr rate order of ZnO nanoparticles on ECSH were also determined. The adsorption of the ZnO nanoparticles was found to increase with increasing contact time with the attainment of equilibrium at 100th minutes with maximum removal efficiency of 85.5% (0.036 mg/g) and 89.6% (0.106 mg/g)  ZnO nanoparticles for laboratory and commercial synthesized ZnO from aqueous solution. An optimum pH of 8 with adsorbent dose of 2.0 g at a temperature of 50 oC gave good results of  ZnO nanoparticles removal. The equilibrium data for both sorbate solution fitted well for both Langmuir and Freundlich isotherm models. From the Langmuir model, ECSH recorded greater sorption capacity of 0.2 mg/g and 0.6 mg/g for both laboratory and commercial synthesized ZnO nanoparticles respectively. The kinetic studies showed pseudo-second order model as the best fitted for the sorption of ZnO nanoparticles for both synthesized samples.

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There is a global need to develop engineering materials to address the increasing demands in various industries. Spark plasma sintering (SPS) is one of the most distinguished powder metallurgy techniques, offering the opportunity for the fabrication of different types of materials. This work emphasizes optimizations of the important process parameters, including temperature, pressure, and holding time, involved in the SPS of the WC, WC-Co, and WC-Cr, as well as assessing the influence of the content of the Co (6-24 wt.%) and Cr (0.2-1 wt.%) binders on the overall characteristics of the SPS-ed cermets. The results illustrate that the process parameters highly affect the physicomechanical properties of the SPS-ed WC, where the most appropriate conditions from a physicomechanical viewpoint are obtained at a sintering temperature of 1700 °C, a pressure of 80 MPa, and a holding time of 5 min. The included Co binder reduces the optimum temperature and pressure down to 1200 °C and 70 MPa, respectively. The addition of the Co improves the final properties of the WC irrespective of its content. The highest tribomechanical properties are attained when 18 wt. % of Co is added. Similar to that of Co, the incorporation of Cr into the WC increases the tribomechanical performance. In general, the use of Co and Cr metallic binders seems a useful strategy to promote the overall properties of the SPS-ed WC.