A. Mohammadzadeh, A. Sabahi Namini, M. Azadbeh,
Volume 11, Issue 3 (september 2014)
Abstract
The rapidly solidified prealloyed alpha brass powder with a size range of 40 to 100 μm produced by water
atomization process was consolidated using liquid phase sintering process. The relationships between sintering
temperature, physic-mechanical properties and microstructural characteristics were investigated. Maximum
densification was obtained at 930 °C, under 600 MPa compacting pressure, with 60 min holding time. The
microstructure of the sintered brass was influenced by dezincification and structural coarsening during supersolidus
liquid phase sintering. As a consequence of Kirkendall effect atomic motion between Cu and Zn atoms caused to
dezincification at the grain boundaries and formation of ZnO particles on the pore surfaces. It was concluded that
microstructural analysis is in a well agreement with obtained physical and mechanical properties. Also, the amount of
liquid phase, which depends on sintering temperature, results in different load bearing cross section areas, and it
affects the type of fracture morphologies.
Mahnaz Mohammadzadeh Mianji, Hossein Sarpoolaky, Mehrnoush Shafiei Sararoudi,
Volume 18, Issue 1 (March 2021)
Abstract
Translucent porcelain with appropriate workability has been considered beneficial for light and shadow to be used in the production of ceramic artworks. In addition, using low firing temperature encourages more artists to use this body. The soft-paste cellulose composite porcelain is composed of similar amount of high Borax/Calcia leadless frit and Kaolin with 3% Vee gum T as a plasticizer. In order to increase workability and green strength, five units of soft-paste porcelain (SP) slip was mixed by one unit bleached bagasse pulp of sugar cane slip in volume and then cellulose containing soft-paste porcelain (CSP) slip was made. The samples were formed by hand, dried and then fired at the optimum temperature of 1120 for 5 hours. Results showed that the SP sample became self-glazed after firing while cellulose increased porosity in CSP. Microstructure analysis showed a large amount of glass phase, which improved translucency of the bodies. Moreover, mullite needle-shaped crystals were derived from the flux-penetrated clay because of less viscous molten body matrix. XRD results clearly showed that the fritted soft-paste porcelain consists of quartz, mullite, anorthite and albite in the fired state. Spectrophotometry showed that adding cellulose to the porcelain body slightly increased translucency in the wavelength ranges 400 to 500 nm.
