Showing 5 results for Baghshahi
A. Izadpanahi, S. Baghshahi, A. Shalbaf Zadeh,
Volume 13, Issue 3 (September 2016)
Abstract
In the following research, Lead magnesium niobate relaxor ferroelectric (PMN-PZT) ceramic powders were synthesized using the combustion method grand urea as the fuel for the first time. The starting materials used were lead nitrate, magnesium acetate, niobium oxide, zirconium nitrate, titanium oxide.
The raw materials were first mixed using the general formula of (1-x)Pb(Mg1/3Nb2/3)O3-xPb(Zr0.52Ti0.48)O3, with x=0.3. The synthesized powders were characterized using XRD, SEM and FTIR spectroscopy techniques. The X-ray diffraction patterns revealed that the structure of the prepared samples were tetragonal at 500,600,700 and 800 oC. However, the monoclinic phase was detected in the samples calcined at 800 oC and the amount of pyrocholore phase also drastically decreased at this temperature. The band gap widths of the samples were measured via UV spectroscopy in the wave number range of 400-4000cm-1. The results show that by increasing the calcination temperature, the band gap width of the prepared samples decreases. SEM micrographs verify that by rising the calcination temperature, the structure of the prepared samples becomes more homogenous.
S.m. Moussavi Janbesarayi, M. Mohebi, S. Baghshahi, S.a. Ahmad Alem, E. Irom,
Volume 17, Issue 2 (June 2020)
Abstract
Overusing nitrogen fertilizer causes some serious problems for water resources, soil, and agriculture products. Researchers have been trying to develop effective means which may use less amount of fertilizers containing nitrogen. In this work, cost-effective ceramic granule adsorbent was prepared to be used as a fertilizer carrier of controlled release behavior. A mixture of 70 wt.% domestic kaolin and 30 wt.% gibbsite was used to produce the granules. By utilizing thermal analysis of raw granule, the calcination temperatures were obtained and the effect of various calcination temperatures of 500, 600, and 700˚C on the water adsorption was studied. The characteristics of granules were investigated by XRD, BET, FTIR, and SEM analyses. The results showed that by increasing the calcination temperature, the crystal structure of the granules was transformed into a dehydrated form and by calcination at 600°C the specific surface area of granules increased from 7.50 to 53.45m2/g. The granules were soaked in a 500g/lit solution of urea, where they adsorbed about 10wt.% urea. The dried urea-loaded granules were placed in water where the release of urea was measured by UV-vis spectrophotometry. Finally, different portions of urea-loaded granules were evaluated as fertilizer in the growing bed of corn plant where the height and the stem diameter of samples were compared with a control sample as well as a sample fertilized by urea directly. The results showed that by using the loaded granules, the urea consumption can be reduced by 50%.
Arian Heidar Alaghband, Azam Moosavi, Saeid Baghshahi, Ali Khorsandzak,
Volume 18, Issue 3 (September 2021)
Abstract
Porous nanostructured SnO2 with a sheet-like morphology was synthesized through a simple green substrate-free gelatin-assisted calcination process using Tin tetracholoride pentahydrate as the SnO2 precursor and porcine gelatin as the template. Crystalline phase, morphology, microstructure, and optical characteristics of the as-prepared material were also investigated at different calcination temperatures using X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), UV-visible absorption, and Photoluminescence spectroscopy (PL), respectively. XRD patterns of all the samples revealed the presence of a tetragonal crystalline structure with no other crystalline phases. Moreover, the synthesized hierarchical sheets assembled with nanoparticles displayed a large surface area and porous nanostructure. The calculated optical band gap energy varied from 2.62 to 2.87 eV depending on the calcination temperature. Finally, photoluminescence spectra indicated that the nanostructured SnO2 could exhibit an intensive UV-violet luminescence emission at 396 nm, with shoulders at 374, violet emission peaks at 405 and 414 nm, blue-green emission peak at 486 nm, green emission peak at 534 nm and orange emission peak at 628 nm.
Pooyan Soroori, Saeid Baghshahi, Arghavan Kazemi, Nastaran Riahi Noori, Saba Payrazm, Amirtaymour Aliabadizadeh,
Volume 19, Issue 3 (September 2022)
Abstract
The goal of the present study is to prepare a room temperature cured hydrophobic and self-cleaning nano-coating for power line insulators. As a result, the installed insulators operating in power lines can be coated without being removed from the circuit and without the need to cut off power. For this purpose, hydrophobic silica nanoparticles were synthesized by sol-gel method using TEOS and HMDS. The synthesized hydrophobic silica nanoparticles were characterized by XRD, FTIR, SEM, and TEM analyses to investigate phase formation, particle size, and morphology. Then the surface of the insulator was cleaned and sprayed by Ultimeg binder solution, an air-dried insulating coating, as the base coating. Then the hydrophobic nano-silica powder was sprayed on the binder coated surface and left to be air-cured at room temperature. After drying the coating, the contact angle was measured to be 149o. Pull-off test was used to check the adhesion strength of the hydrophobic coating to the base insulator. To evaluate the effect of environmental factors, UV resistance and fog-salt corrosion tests were conducted. The results showed that 150 hours of UV radiation, equivalent to 9 months of placing the samples in normal conditions, did not have any significant effect on reducing the hydrophobicity of the applied coatings.
Saba Payrazm, Saeid Baghshahi, Zahra Sadeghian, Amirtaymour Aliabadizadeh,
Volume 19, Issue 3 (September 2022)
Abstract
In this research, zinc oxide quantum dots and graphene nanocomposites were synthesized via two different methods; In the first (direct) method, ZnO-graphene Nanocomposites were made mixing the synthesized zinc oxide and graphene. In the second (indirect) method, zinc nitrate, graphene, and sodium hydroxide were used to made ZnO-graphene Nanocomposites. XRD, FTIR and Raman spectroscopy analyses were used for phase and structural evaluations. The morphology of the nanocomposites w::as char::acterized by SEM. The specific surface area and porosity of the samples were characterized by BET analysis. The optical properties of the samples were investigated by photoluminescence and ultraviolet-visible spectroscopy analyses. Results showed that using graphene, increased the photoluminescence property and shifted the photoluminescence spectrum of the composites towards the visible light spectrum. The photoluminescence of the synthesized graphene-zinc oxide composite, in the visible light region, was closer to white light than that of pure zinc oxide. According to the results of BET test, the nanocomposite synthesized by direct method had a higher surface area (25.7 m2.g-1) and a higher porosity (0.32 cm3.g-1) than the nanocomposite synthesized by the indirect method with a specific surface area of (16.5 m2.g-1) and a porosity of 0.23 cm3.g-1).
